Honda’s New Fl-Ion Battery Chemistry

Discussion in 'In the News' started by xcel, Dec 6, 2018.

  1. xcel

    xcel PZEV, there's nothing like it :) Staff Member

    [​IMG] Up to 10 times the energy density of Li-Ions!

    Wayne Gerdes – CleanMPG – December 6, 2018


    Scientists from Honda Research Institute have collaborated with researchers at California Institute of Technology (Caltech) and NASA's Jet Propulsion Laboratory to develop a new battery chemistry that enables the use of materials with higher energy density and a more favorable environmental footprint than current battery technologies. The collective team of scientists co-authored a new paper on the topic that was published in Science and is available at Room-temperature cycling of metal fluoride electrodes: Liquid electrolytes for high-energy fluoride ion cells.

    The joint study reports that the research team has opened new doors in the development of high energy-density batteries capable of meeting rapidly growing energy storage needs by overcoming the current temperature limitations of fluoride-based battery (FIB) technology and by demonstrating the room-temperature operation of fluoride-ion based energy cells.

    Dr. Christopher Brooks, Chief Scientist, Honda Research Institute, and a co-author of the paper:
    FIBs provide an attractive alternative to other types of potential high-energy battery electrochemistries, such as those based on lithium- or metal hydride chemistries, which are generally limited by the inherent properties of their electrodes. Due to the low atomic weight of fluorine, rechargeable batteries based on the element could offer very high energy densities–up to 10 times greater than the theoretical values for lithium-ion technologies. However, while FIBs are considered a strong contender for the "next-generation" of high-density energy storage devices, they are limited by their required temperature requirements.

    Currently, solid-state fluoride ion-conducting battery iterations need to operate at elevated temperatures–above 150 degrees Celsius–to make the electrolyte fluoride-conducting. According to the paper's authors, these limitations in the electrolyte have presented a significant challenge for achieving low-temperature operating FIBs.

    To address this, the research team found a method for creating a fluoride-ion electrochemical cell capable of operating at room temperature–a breakthrough made possible by a chemically stable liquid fluoride-conducting electrolyte with high ionic conductivity and a wide operating voltage. The scientists developed the electrolyte using dry tetraalkylammonium fluoride salts dissolved in an organic, fluorinated ether solvent. When paired with a composite cathode featuring a core-shell nanostructure of copper, lanthanum and fluorine, the researchers demonstrated reversible electrochemical cycling at room temperature.

    In the future, FIBs could power battery-electric vehicles. The higher-capacity nature of the battery makes it a good candidate for power products as well.

    A PR with lab breakthroughs is all well and good. The real question can this breakthrough scale up and for a cost that makes sense? I have no answer for that and Honda was not forthcoming either.
  2. Trollbait

    Trollbait Well-Known Member

    Still in the lab, but if it works out, EV aircraft could become viable.
  3. priusCpilot

    priusCpilot George

    Let's see in 10 years I guess if this makes it.
  4. EdwinTheMagnificent

    EdwinTheMagnificent Legend In His Mind

    I'm guessing that this paper was published simultaneously with a patent application.
    But who will hold the patent ? And will the technology actually work ?
  5. Carcus

    Carcus Well-Known Member

    24M to Unveil Novel Dual Electrolyte System for High Energy Density (+ 350 Wh/kg) Batteries at the International Battery Seminar & Exhibit"

    “Using compositionally distinct electrolytes is a game changer for battery manufacturing and we’ve proven the fundamental technology,” said Rick Feldt, President and CEO of 24M. “At the conference, Naoki will discuss how the 24M Dual Electrolyte System expands the universe of potential electrolytes, including water and other materials that to-date have not been compatible with both the anode and cathode simultaneously.”

    The architecture of the 24M cell and manufacturing process for SemiSolid electrodes have been proven via many tens-of-thousands of cells over the past eight years of development. This work has laid the foundation for the development of the Dual Electrolyte System, the initial testing of which will be discussed at the seminar.

    “The unique 24M approach to compositionally distinct electrolytes makes it possible for 24M to embark on radical new directions in anode and cathode chemistry,” said Koji Hasegawa, General Manager, Industrial Chemicals Department, Itochu Corporation. “Seldom in lithium-ion battery development has such a possibility been realizable, but the advancement in solid-state ion conductors and 24M’s SemiSolid electrodes opens this possibility.”
    xcel likes this.

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